explain why the boiling clues of aldehydes and also ketones are greater than those that ethers and also alkanes of similar molar masses however lower than those of equivalent alcohols. Compare the solubilities in water of aldehydes and ketones of four or fewer carbon atoms through the solubilities of equivalent alkanes and alcohols. Surname the common reactions take ar with aldehydes and ketones. Define some that the provides of typical aldehydes and ketones.

You are watching: Why are alcohols more polar than ketones


In aldehydes and also ketones, this charge separation leader to dipole-dipole interactions the are great enough come significantly impact the boiling points. Table (PageIndex1) shows that the polar single bonds in ethers have tiny such effect, vice versa, hydrogen bonding between alcohol molecules is even stronger.

Table (PageIndex1): Boiling points of link Having similar Molar Masses but Different varieties of Intermolecular pressures CompoundFamilyMolar MassType that Intermolecular ForcesBoiling point (°C)
CH3CH2CH2CH3 alkane 58 dispersion only –1
CH3OCH2CH3 ether 60 weak dipole 6
CH3CH2CHO aldehyde 58 strong dipole 49
CH3CH2CH2OH alcohol 60 hydrogen bonding 97

Formaldehyde is a gas at room temperature. Acetaldehyde boils at 20°C; in an open up vessel, that boils far in a warmth room. Many other usual aldehydes room liquids in ~ room temperature.

The oxygen atom of the carbonyl group engages in hydrogen bonding v a water molecule.


The aldehydes are, in fact, among the most easily oxidized of organic compounds. They room oxidized by oxygen (O2) in air to carboxylic acids.

<2RCHO + O_2 ightarrow 2RCOOH label14.10.1>

The ease of oxidation help starrkingschool.netists determine aldehydes. A sufficiently mild oxidizing agent can identify aldehydes not only from ketones but additionally from alcohols. Tollens’ reagent, for example, is an alkaline equipment of silver- (Ag+) ion complexed through ammonia (NH3), i beg your pardon keeps the Ag+ ion in solution.

When Tollens’ reagent oxidizes one aldehyde, the Ag+ ion is diminished to totally free silver (Ag).


Deposited ~ above a clean glass surface, the silver- produces a mirror (Figure (PageIndex1)). Simple ketones perform not react through Tollens’ reagent.

number (PageIndex1): Aldehyde Reactions. A reaction pertained to the Tollens’ reaction is often used to silver mirrors. These ornaments were silvered by together a reaction. Glucose, a simple sugar with an aldehyde practical group, is used as the reducing agent. Source: photo courtesy of Krebs Glas Lauscha, commons.wikimedia.org/wiki/File:Silvering.jpg.

Although ketones withstand oxidation by simple laboratory oxidizing agents, they undergo combustion, as perform aldehydes.

Some typical Carbonyl Compounds

Formaldehyde has an irritating odor. Since of the reactivity, the is daunting to manage in the gas state. For plenty of uses, it is therefore dissolved in water and sold as a 37% to 40% aqueous solution referred to as formalin. Formaldehyde denatures proteins, calculation them insoluble in water and resistant to bacterial decay. For this reason, formalin is used in embalming solutions and in preserving organic specimens.

Aldehydes are the energetic components in countless other acquainted substances. Big quantities that formaldehyde are offered to do phenol-formaldehyde materials for gluing the lumber sheets in plywood and also as adhesives in other building materials. Sometimes the formaldehyde escapes indigenous the materials and also causes health problems in part people. When some people seem unaffected, others experience coughing, wheezing, eye irritation, and also other symptoms.

The odor of eco-friendly leaves is early in part to a carbonyl compound, cis-3-hexenal, i m sorry with connected compounds is provided to impart a “green” organic odor come shampoos and also other products.

Acetaldehyde is an extremely volatile, colorless liquid. The is a starting material because that the preparation of plenty of other essential compounds. Acetaldehyde is created as a metabolite in the fermentation of sugars and also in the detoxification the alcohol in the liver. Aldehydes space the active components of numerous other acquainted materials (Figure (PageIndex2)).

See more: Ham Is Richard Linklater Related To Art Linkletter Show? Hamish Linklater Biography How To Write



The polar carbon-to-oxygen dual bond causes aldehydes and ketones to have greater boiling points 보다 those the ethers and also alkanes of comparable molar masses but lower 보다 those of equivalent alcohols that interact in intermolecular hydrogen bonding. Aldehydes are easily oxidized to carboxylic acids, whereas ketones resist oxidation.